Forensic Engineers and Consultants

Archive: Chemical

One of the Most Amazing Compounds Around – Water?!?!

Around Christmas day of 2022, a mass of very cold air settled in the deep south/southeastern United States (where I live).  It remained below freezing for over 24 hours.  That is very unusual down here.  There was a spate of burst pipes all over the area.  Why?  Water is one of a very few compounds that expands when it freezes…by approximately 9%!!  If a volume of water is sealed off in a section of piping, and that water freezes, it is likely the pipe will rupture. Then, when it warms up again and thaws, liquid water will leave the pipe for an adventure!! Read More

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Interpreting Industrial Incident Data – Lesson Learned

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This is a case study about an incident I investigated involving a major upset in a distillation column.  This blog builds on the previous blogs about the Distributed Control System, DCS – Data is the Key.

Distillation is a method of separating mixtures of compounds with differing boiling points.  Uncle Bill with his still on the hill separates ethanol, that boils at 173°F, from water that boils at 212°F.  If the mixture is heated to above 173°F, but below 212°F, the ethanol will boil, the vapor will travel up out of the unit and then can be condensed and served over ice with an olive…   Any mixture of two or more chemicals with different boiling points can be separated in this way.  The distillation Read More

WARREN WEBINAR: Property Claims Issues at Manufacturing Facilities

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LIVE WEBINAR: “Property Claims Issues at Manufacturing Facilities” | Presented by WARREN’s President and Senior Consulting Engineer, Jennifer Morningstar, P.E., CFEI.

COURSE LEARNING OBJECTIVES
The learning objectives of this course are to provide the attendees with information on the four major facets of property claims that are commonplace in manufacturing facilities.

They are:

  1. Subrogation against third parties;
  2. Boiler & machinery vs property claims;
  3. Scope of loss, and
  4. Business interruption

Each facet will be explored and exemplified by at least one case study.

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The Paths of Chemical Exposure

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The Safety Hierarchy states that hazards should be mitigated first by engineering controls, secondly by guarding, and lastly by warning/training.  When the first two, engineering controls and guards, fail in a manufacturing setting, a chemical release could occur. A forensic chemical engineer can help determine the root cause of that failure. Read More

Ammonia – The Good, The Bad, The Smelly… Part Two

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Now that you know what ammonia is (see Part One here), how it behaves, and how to safely store it and work with it, let’s look at some areas in industry where it is used.

Anhydrous ammonia has a use in pollution control.  Industrial boilers and power plants burn coal or natural gas to make steam and/or electricity. When the fuel is burned using air as the oxygen source nitrogen gets exposed to the heat as well because air is 79% nitrogen.  The nitrogen gets oxidized and forms several compounds referred to as NOx (NO, NO2, NO3).  NOx compounds are harmful to Read More

Ammonia

Ammonia – The Good, The Bad, The Smelly… Part One

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Ammonia is a compound consisting of one nitrogen atom and three hydrogen atoms and is denoted by the formula NH3. Its boiling point is -28°F at atmospheric pressure, so unless it is under pressure, it is gaseous at room temperatures. Therefore, pure ammonia is typically stored under pressure in a liquid form. Household ammonia is only 5-10% NH3, the remaining 90-95% is water. Ammonia is extremely soluble in water. It is often depicted  like this: Read More

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